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DAUBEN SALEM TURRO ANALYSIS The following very useful approach for the analysis of photochemical reactions is due to Dauben, Salem, and Turro [13] A bond, a b, made from fragment orbitals fa and fb of molecular fragments, a and b, is broken in the process under consideration The relationship to the orbital interaction diagram is transparent (see Figure 153) The orbitals fa and fb are the left- and right-hand sides of the interaction diagram, while the assembly a b is the middle The ``middle'' constitutes the reactant The noninteracting rightand left-hand sides constitute the products Assume that the orbital fb is lower in energy than fa .

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Jan 19, 2016 · Convert Tiff file into PDF file using iTextSharp DLL. iTextSharp.text.pdf.PdfWriter writer = iTextSharp.text.pdf.PdfWriter.GetInstance(document, new System.IO.FileStream(destPdf, System.IO.FileMode.Create)); System.Drawing.Bitmap bmp = new System.Drawing.Bitmap(sourceTif); iTextSharp.text.pdf.PdfContentByte cb = writer ...

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The two electrons originally in the bonding orbital may be distributed in four distinct ways between the two fragment orbitals, fa and fb , yielding four states, Z1 F F F fb 2 fa 0 , Z2 F F F fb 0 fa 2 , 1 D F F F fb 1 fa 1 , and 3 D F F F fb 1 fa 1 The rst two states are zwitterionic, since the bond dissociates heterolytically Also, since both electrons occupy the same orbital, both zwitterionic states are singlet states and will be totally symmetric with respect to any symmetry operation which may be preserved in the dissociation By our assumption that E fb ` E fa , it is expected that E Z1 ` E Z2 The remaining two states arise from homolytic dissociation of the bond and therefore are diradical in character Both singlet and triplet states arise.

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If any residual interaction persists (ie, if the bond broken was a p bond or the products are held together in a solvent cage), then the triplet diradical state is lower than the singlet diradical state Otherwise the two have the same energy Since the electrons end up in di erent orbitals, the spatial symmetry of the diradical states is determined by the symmetry properties of fa and fb The diradical is symmetric (S) if fa and fb are both.

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